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Molecular arrangement controls crystal polarity and reverses photocurrent direction
Researchers at Science Tokyo have shown that the circular photogalvanic effect in two-dimensional organic-inorganic hybrid perovskites arises from the crystal bulk rather than its surface. Using circularly polarized light at normal incidence, they found helicity-dependent photocurrents that reversed with light handedness and with crystal polarity in chiral enantiomers. The lead iodide layers provide strong spin-orbit coupling while molecular cations set bulk polarity.
Oct 83 min read
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